| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1386004 | Carbohydrate Polymers | 2009 | 5 Pages |
Abstract
A facile method to obtain novel sucrose polymers is reported. These polymers were obtained by means of the Thiol-Ene photopolymerization technique. The sucrose was functionalized with allyl groups by etherification with allyl bromide and then photopolymerized by the step-growth mechanism with multifunctional thiols. The kinetics of photopolymerization were determined by optical pyrometry and Real-Time FT-IR. It was found that this photocurable system was highly reactive obtaining solid crosslinked polymers that displayed high uniformity in the crosslink density. A Tg of 58 °C was determined by means of DMA for the polymer derived from A2S and PETKMP. The prepared polymers displayed thermal stability up to 230 °C.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ricardo Acosta Ortiz, Aida E. Garcia Valdéz, Marty Georgina Martinez Aguilar, Maria Lydia Berlanga Duarte,