Article ID Journal Published Year Pages File Type
1387820 Carbohydrate Research 2012 9 Pages PDF
Abstract
► DFT calculations reveal relative stabilities of conformers of inositol 1,3-acetals. ► Relative stability of conformers provide insight into mechanism of deoxygenation. ► Deoxygenation of myo- and neo-xanthates proceeds through a common transition state.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Radical mediated deoxygenation of inositol benzylidene acetals: conformational analysis, DFT calculations, and mechanism
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