Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1387895 | Carbohydrate Research | 2014 | 8 Pages |
Abstract
•Key intermediate 9 was prepared from d-(−)-isoascorbic acid as well as d-ribose.•Bio-active compounds 1, 4, and 5 were obtained from a common intermediate 18.•Grubbs RCM, Morita–Baylis–Hillman (MBH), and Luche reductions are key steps.
Asymmetric total synthesis of (+)-gabosine C, (+)-pericosine B, and (+)-pericosine C has been reported from readily available d-(−)-isoascorbic acid and d-ribose involving Grubbs ring closing metathesis, Morita–Baylis–Hillman (MBH) reaction, and Luche reduction.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
D. Chanti Babu, Ch. Bhujanga Rao, K. Venkatesham, J. Jon Paul Selvam, Y. Venkateswarlu,