| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1388095 | Carbohydrate Research | 2010 | 5 Pages |
Abstract
Treatment of peracetylated alkyl and aryl 1,2-trans-glycosides with iodine in the presence of HMDS has been found to result in the anomerization leading to the formation of the respective 1,2-cis-glycosides. In the case of alkyl glycosides with aglycons of short alkyl chain length complete anomerization to the α-glycosides was observed while with those of longer chain length the process was found to be incomplete. The observations have been interpreted mechanistically.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Satish Malik, Krupesh J. Shah, K.P. Ravindranathan Kartha,