Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1388672 | Carbohydrate Research | 2009 | 6 Pages |
Abstract
Ethyl 6-O-acetyl-2,3,4-tribenzyl-1-thio-d-glucopyranoside, as a mixture of anomers, was employed for the stereoselective synthesis of the potassium salt of (2R)-2-O-α-d-glucopyranosyl-(1→6)-α-d-glucopyranosyl-2,3-dihydroxypropanoic acid (α-d-glucosyl-(1→6)-α-d-glucosyl-(1→2)-d-glyceric acid, GGG), a recently isolated compatible solute. The α-anomer was by far the major product of both glycosylation reactions using NIS/TfOH as activator.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Eva C. Lourenço, Christopher D. Maycock, M. Rita Ventura,