| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1388994 | Carbohydrate Research | 2009 | 8 Pages |
Abstract
The first syntheses of two deoxythiocyanocyclitols (4-deoxy-4-thiocyano-l-chiro-inositol and deoxythiocyanoconduritol F) and two deoxysulfonylcyclitol acetals are reported by a chemoenzymatic enantioselective route. The compounds were prepared by a sequence of enzymatic and ruthenium-catalyzed dihydroxylations, and the results were studied regarding reaction conditions and co-catalyst for different derivatives. The new compounds were included in a minilibrary of deoxygenated cyclitols and evaluated for their capacity to influence the feeding behavior of Epilachna paenulata (Coleoptera: Coccinellidae), a common pest of the Curcubitaceae crops.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ana Bellomo, Soledad Camarano, Carmen Rossini, David Gonzalez,