| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1389097 | Carbohydrate Research | 2005 | 4 Pages |
Abstract
The significant excess in conformational free-energy at position 2 of an oxane ring and other chemical and physical properties are explained by an anomeric effect of the proton.
Graphical abstractThe 2p lone-pair orbital of the oxygen atom in oxane is delocalized into the adjacent axial C–H bond.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Serge David,