| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1389117 | Carbohydrate Research | 2007 | 6 Pages |
Abstract
Different deallylation methods were assayed for selective deprotection of allyl galactopyranosiduronic acid derivatives. A two-step procedure using DABCO and (Ph3P)3RhCl followed by mercuric-assisted cleavage gave quantitative yields. Reaction in the presence of [18O]water allowed us to obtain evidence about the mechanism of prop-1-enyl cleavage.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Maximilien Barbier, Eric Grand, José Kovensky,