| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1389801 | Carbohydrate Research | 2008 | 5 Pages |
Abstract
A novel route to glycosylamines has been developed. Treatment of glycosyl trichloroacetimidates with TMSOTf under glycosylation conditions, but in the absence of an acceptor, resulted in complete rearrangement of the trichloroacetimidates into the corresponding N-protected-glycosylamines. Reductive cleavage of the trichloroacetyl groups using sodium borohydride provided the desired glycosylamine products.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kim Larsen, Carl Erik Olsen, Mohammed Saddik Motawia,