Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1390480 | Carbohydrate Research | 2011 | 4 Pages |
Abstract
Commercially available zinc dust in the presence of ammonium chloride in acetonitrile at reflux removes the 2,2,2-trichloroethyl (TCE) group at anomeric centers with excellent yields (>95%) in short reaction times. This present method is easily implemented on substrates containing acyl and benzyl groups and large-scale reactions also proceed in high yield.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jianbo Zhang, Jie Fu, Wenshuai Si, Xiaohu Wang, Zhongfu Wang, Jie Tang,