Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1390886 | Carbohydrate Research | 2007 | 8 Pages |
Abstract
Carbohydrate-based vinyl selenides of the arabino, ribo and 2-deoxy-ribo configuration have been prepared by Wittig-type reactions of various protected furanoses. Moderate yields were always obtained due to the nature and reactivity of both carbohydrate lactols and selenium-based olefinating reagents under the conditions tested. A detailed study of the olefination reaction and the behaviour of vinyl selenides towards the electrophilic-induced cyclization will be discussed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Omar Boutureira, M. Isabel Matheu, Yolanda Díaz, Sergio Castillón,