Article ID Journal Published Year Pages File Type
1390963 Carbohydrate Research 2006 10 Pages PDF
Abstract

exo-Glycosyl carbonates were employed for inter- and intramolecular glycosylation reactions. A number of metallic Lewis Acids and solvents were examined to enhance the reactivity. The optimum conditions were found to be the use of AlCl3 in 1-nitropropane. The method was demonstrated to be useful for the intermolecular glycosyl transfer of several nucleophiles, including simple alcohols, sugars, and amino acid derivatives; however, intramolecular glycosylations were not successful.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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