Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1390963 | Carbohydrate Research | 2006 | 10 Pages |
Abstract
exo-Glycosyl carbonates were employed for inter- and intramolecular glycosylation reactions. A number of metallic Lewis Acids and solvents were examined to enhance the reactivity. The optimum conditions were found to be the use of AlCl3 in 1-nitropropane. The method was demonstrated to be useful for the intermolecular glycosyl transfer of several nucleophiles, including simple alcohols, sugars, and amino acid derivatives; however, intramolecular glycosylations were not successful.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sheng-Jie Hsu, Hui-Chang Lin, Chun-Hung Lin,