| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1396016 | European Polymer Journal | 2011 | 9 Pages |
Two hydrophilic branched oligo(ethylene glycol)-substituted PPV derivatives, poly(2,5-bis(1,3-bis(triethoxymethoxy)propan-2-yloxy)-1,4-phenylene vinylene) (BTEMP-PPV) and poly(2-methoxy-5-(1,3-bis(triethoxymethoxy)propan-2-yloxy)-1,4-phenylene vinylene) (MTEMP-PPV), are presented. Polymerizations have been performed via the dithiocarbamate precursor route, using lithium hexamethyldisilazide (LHMDS) as a base, to obtain high molecular weight precursor polymers. After thermal conversion of the precursor polymers into the fully conjugated systems, the solubility of the polymers has been examined. The polar nonionic side chains of MTEMP-PPV and BTEMP-PPV render the PPV backbone soluble in a variety of solvents, including alcohols and even water, making these polymers suitable candidates to be used in optoelectronic devices that can be processed from environmentally friendly solvent systems.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Synthesis of highly polar MTEMP-PPV and BTEMP-PPV via the dithiocarbamate route. ► The polymers are soluble in alcohols and water. ► Impedance spectroscopy revealed a high relative permittivity for MTEMP-PPV. ► Film morphology optimization is required to increase the hole mobility. ► A concept solar cell device has been processed from an environment-friendly solvent.
