Triphenylamine and quinoline-containing polyfluorene for blue light-emitting diodes

A novel blue light-emitting polyfluorene-based copolymer PTHD containing electron-rich triphenylamine and electron-poor phenylquinoline side chains in the C-9 position of fluorene unit is described. By comparison of the solution and thin film photoluminescence (PL) spectra of PTHD, a considerable red-shift of Δλ = 10–15 nm was observed in the thin film PL spectrum. The emission intensity of the shoulder peak appeared in dilute solution was also significantly enhanced in the thin film. In contrast to the reference polymer poly{[9,9-dihexylfluorene]-alt-[9,9-di(2,4-diphenylquinoline)fluorene]}, PTHD exhibits higher HOMO energy level, and higher maximum brightness with the PLED device configuration of ITO/PEDOT:PSS/polymer70% + PBD30%/TPBI/LiF/Al.

Graphical abstractA new blue light-emitting polyfluorene derivative PTHD incorporated triphenylamine and quinoline moieties as side chains was synthesized by Suzuki coupling reaction.Figure optionsDownload full-size imageDownload as PowerPoint slide