Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1396353 | European Polymer Journal | 2009 | 7 Pages |
Abstract
In this report, we describe the synthesis and characterization of photosensitive poly(l-lactide) with a pendent cinnamate group. α,Ï-Dihydoxy terminated poly(l-lactide) (PLLA-diol) [molecular weights (MW); 2000, 4000 and 9000 g/mol ] was chain-extended with a diacyl chloride of 5-cinnamoyloxyisophthalic acid (ICA) to obtain high-molecular-weight photocrosslinkable poly(l-lactide)s (ICA/PLLA). The resulting polyesters were characterized by proton nuclear magnetic resonance spectroscopy, gel permeation chromatography, ultraviolet-visible spectroscopy, differential scanning calorimetry, thermomechanical analysis and thermogravimetry. The glass transition temperature (Tg), the melting temperature (Tm) and the degree of relative crystallinity (Xc) of ICA/PLLAs increased with the increasing MW of the PLLA-diols. The photosensitive ICA/PLLAs were irradiated with a 400 W high-pressure mercury lamp (λ > 280 nm) for various times to produce the PLLA gel films without a photoinitiator. The crosslinking rate monitored by a UV-vis spectrum decreased with the increasing MW of the PLLA-diols. The crosslinking of the ICA/PLLA â4000 film enhanced the Tg slightly and the tensile strength and Young's modulus significantly, while reduced the Tm and Xc. The enzymatic degradation was measured by the weight loss of the films in a phosphate buffer solution with proteinaze-k. The crosslinking of the films decreased markedly the degradation rate.
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Authors
Minoru Nagata, Kunihito Inaki,