Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1397114 | European Polymer Journal | 2005 | 7 Pages |
Abstract
Novel transesterification of acetylated maritime pine sapwood (Pinus pinaster Soland) reaction was performed with tetramethoxysilane (TMOS) in presence of dibutyltin oxide as a catalyst. Transesterification was confirmed by weight percent gain calculations (WPG), infrared spectroscopy (FTIR) as well as 13C and 29Si NMR CP-MAS analysis. The results showed that transesterification indeed occurs via exchange of acetate groups from acetylated wood and methoxysilane groups from TMOS. The effect of temperatures and reaction time upon transesterification efficiency was also investigated.
Related Topics
Physical Sciences and Engineering
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Authors
Nihat Sami Çetin, Nilgül Özmen, Philippe Tingaut, Gilles Sèbe,