| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1399613 | European Polymer Journal | 2013 | 9 Pages |
•PU/PLA/CNT composites were prepared by melt blending and investigated its properties.•Improvement in properties was observed on loading modified CNT in PU/PLA blend.•Shape memory study showed high speed recoverability on loading modified CNT in blend.
Polymer blend nanocomposites based on thermoplastic polyurethane (PU) elastomer, polylactide (PLA) and surface modified carbon nanotubes were prepared via simple melt mixing process and investigated for its mechanical, dynamic mechanical and electroactive shape memory properties. Chemical and structural characterization of the polymer blend nanocomposites were investigated by Fourier Transform infrared (FT-IR) and wide angle X-ray diffraction (WAXD). Loading of the surface modified carbon nanotube in the PU/PLA polymer blends resulted in the significant improvement on the mechanical properties such as tensile strength, when compared to the pure and pristine CNT loaded polymer blends. Dynamic mechanical analysis showed that the glass transition temperature (Tg) of the PU/PLA blend slightly increases on loading of pristine CNT and this effect is more pronounced on loading surface modified CNTs. Thermal and electrical properties of the polymer blend composites increases significantly on loading pristine or surface modified CNTs. Finally, shape memory studies of the PU/PLA/modified CNT composites exhibit a remarkable recoverability of its shape at lower applied dc voltages, when compared to pure or pristine CNT loaded system.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
