Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1400069 | European Polymer Journal | 2008 | 6 Pages |
Abstract
The radicals formed upon visible light irradiation of the photoinitiator 2-benzyl-2-dimethylamino-4′-morpholinobutyrophenone (Irgacure 369), 1, were investigated by means of EPR spectroscopy coupled with the spin trapping technique both in the absence and in the presence of a monomer. The results suggest a dual behavior of 1 that may act both as a Type I and a Type II photoinitiator. From experiments carried out in the presence of 2-ethoxythioxanthone (Pila 124), 2, an additive commonly used in combination with 1 as sensitizer, it is inferred that 2 mainly acts via hydrogen abstraction from 1.
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Authors
Angelo Alberti, Massimo Benaglia, Dante Macciantelli, Stefano Rossetti, Marco Scoponi,