Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1400253 | European Polymer Journal | 2006 | 9 Pages |
Well-defined polystyrenes and poly(n-butyl acrylate)s of the two ends being functionalized with terpyridine groups were synthesized via addition-fragmentation chain transfer (RAFT) polymerization using a symmetric bisterpyridine-functionalized trithiocarbonate as a chain transfer agent (CTA). Kinetic studies on RAFT mediated thermal polymerization of styrene indicated the controlled polymerization. Corresponding triblock copolymers of styrene and n-butyl acrylate were obtained by utilizing the bisterpyridine-functionalized homopolymers as the macro-CTAs. Supramolecular metallo-polystyrenes with different repeat blocks were prepared by the chelating interaction between the terpyridine ends and Ru(II) ions. The formation of the metallo-polymers was proven by UV–vis spectra and dynamic light scattering (DLS).