| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1400408 | European Polymer Journal | 2015 | 10 Pages |
•Single step bio-based products by click chemistry.•Thiol-ene of mercaptanized soybean oil and functionalized allyl compounds.•Polyamines, epoxides, isocyanates, isothiocyanates and silicon compounds.•Precursors for foams adhesives, coatings, sealants and elastomers.
A range of vegetable oil derivatives with hydroxyl, amine, isocyanate, isothiocyanate, epoxy and silane terminal groups, useful for making new bio-based polymers, were synthesized from mercaptanized oils and different allyl organic compounds by thiol-ene reaction. All products were low viscosity liquids of light yellow color except amine containing oil, which was a low melting solid. Novel functionalized oils had 3–6 functional groups per mole and were suitable for rigid and flexible polymer products.
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