Frontal photopolymerization synthesis of multilayer hydrogels with high mechanical strength

Multilayer hydrogels were prepared by frontal photopolymerization of acrylamide and 2-acrylamido-2-methylpropane sulfonic acid using hydrophilic reactive microgels (HRM) as crosslinkers instead of conventional crosslinkers. The hydrophilic microgels (HM) were prepared by inverse emulsion photopolymerization and then were chemical modified by N-methylolacrylamide (NMA) to obtain HRM with CC double bonds. The HM and HRM was characterized by dynamic light scattering measurements, SEM, TEM and FTIR, respectively. It was found that the resulting multilayer hydrogels showed high fracture strength and high tensile elongation along parallel direction. However their fracture strength and tensile elongation along perpendicular direction was very weak. The swollen multilayer hydrogels were about 1.0–2.0 mm in thickness, the maximal equilibrium swelling degree was only 30.45. The multilayer hydrogels were characterized by DSC, TEM and XRD, respectively. The swelling property and mechanical strength of some typical multilayer hydrogels were studied.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Multilayer hydrogels were prepared by frontal photopolymerization. ► Hydrophilic reactive microgels (HRM) containing CC double bonds as crosslinkers. ► The multilayer hydrogels showed high mechanical strength along parallel direction. ► The multilayer hydrogels were very weak along perpendicular direction.