Article ID Journal Published Year Pages File Type
1401028 European Polymer Journal 2008 6 Pages PDF
Abstract

The free-radical copolymerization of two N-substituted acrylamide monomers, the ionic AMPS (2-acrylamido-2-methyl-1-propanesulfonic acid) and the non-ionic HEAm (2-hydroxyethylacrylamide) is presented. Despite bearing similar polymerizable functionalities, HEAm is more reactive toward free-radical addition than AMPS in water. In a mixed aqueous solvent containing salt, (0.5 M LiNO3, 50 wt%) and ethanol (50 wt%), the reactivity ratio was found to be rAMPS = 0.53 and rHEAm = 1.06 indicating that copolymers with a nearly random distribution of sulfonic and hydroxy functionalities can be prepared.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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