Nucleation of crystallization in isotactic polypropylene and polyoxymethylene with poly(tetrafluoroethylene) particles

Nucleation of crystallization of isotactic polypropylene (iPP) and polyoxymethylene (POM) with dispersed submicron particles of another polymer – poly(tetrafluoroethylene) (PTFE) was studied. The polymers were mixed with various contents of PTFE particles, in the range from 0.005 to 0.5 wt.%. iPP and POM with PTFE particles are all-polymer systems with enhanced nucleation of crystallization. PTFE particles with sizes below 300 nm added to POM and iPP efficiently decreased sizes of polycrystalline aggregates. Moreover, nonisothermal crystallization temperature of iPP by increased by up to 14 °C. iPP and POM with PTFE exhibited the elastic modulus slightly higher, by up to 10–13%, than that of the neat polymers. Other mechanical properties remained unchanged, with the exception of reduced elongation at break of POM with PTFE.

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