| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1402239 | European Polymer Journal | 2010 | 10 Pages |
A series of dihydroxyl telechelic poly(alkyl-phenylene oxide)s (1) have been synthesized by oxidative polymerization of alkylphenols with various aromatic diols using manganese or copper amine catalysts. The novel telechelic derivatives (1) were epoxidized with epichlorohydrin yielding a series of new epoxidized poly(alkyl-phenylene oxide)s (EPPO, 2) and the structures, properties were studied by nuclear magnetic resonance spectroscopy (NMR), differential scanning calorimetry (DSC), thermo gravimetric analysis (TGA) and gel permeation chromatography (GPC). The 1:1 blends of diglycidyl ether of bisphenol-A (DGEBA) with EPPO resins were cured with three curing agents and the effects of chemical structure change on thermal property of the curing matrixes were discussed. Incorporation of EPPOs to DGEBA epoxy system resulted in a significant increase in its glass transition temperature (Tg), thermal stability and flame resistance. The Tg values and char yields arising from a DDM-cured epoxy resin are usually higher than those of dicyandiamide (DICY) or 2-methylimidazole (2-MI) analogues and the reactivity of epoxy blends with three curing agents presents an increase in the order of 2-MI, DDM and DICY. In general, the tetramethylbisphenol-A (TMBPA)-derived polymer exhibits the lowest Tg, char yield and dielectric constant among PPO derivatives whereas the biphenol polymers usually results in higher Tg and char yield due to its rigid rod structure.
Graphical abstractTelechelic poly(alkyl-phenylene oxide)s bearing dihydroxyl or diglycidyl ether functional groups on both ends have been successfully synthesized and characterized. The blends of DGEBA with EPPO resins were cured with various amine hardeners and the effects of chemical structure change on thermal property of the curing matrixes were explored.Figure optionsDownload full-size imageDownload as PowerPoint slide
