Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1403807 | European Polymer Journal | 2007 | 6 Pages |
Abstract
A family of aluminum-methyl complexes supported by tetradentate phenoxy-amine ligands has been prepared and employed in the ring-opening polymerization of rac-lactide; the ligands include N,N-bis(3,5-dimethyl-2-hydroxybenyl)-N′,N′-dimethyl-1,2-diaminoethane (L1), N,N-bis(3,5-diisopropyl-2-hydroxybenyl)-N′,N′-dimethyl-1,2-diaminoethane (L2) and N,N-bis(3,5-dichloro-2-hydroxybenyl)-N′,N′-dimethyl-1,2-diaminoethane (L3). Polymerizations of rac-lactide were carried out by treatment of the aluminum-methyl complexes with PhCH2OH and rac-lactide at 70 °C, affording well-controlled formation of polylactide (PLA) and a moderate isotactic bias for initiators bearing L1 and L2; the chloro-substituted ligand L3 afforded largely atactic PLA.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Zhaohui Tang, Vernon C. Gibson,