Article ID Journal Published Year Pages File Type
1416598 Carbon 2011 32 Pages PDF
Abstract

Semiconductor photocatalysis has important applications such as achieving sustainable energy generation and treating environmental pollution. TiO2 has been the most widely-researched photocatalyst, but suffers from low efficiency and narrow light response range. Combining TiO2 with carbonaceous nanomaterials is being increasingly investigated as a means to increase photocatalytic activity, and demonstrations of enhancement are plentiful. This review surveys the literature and highlights recent progress in the development of nanocarbon-TiO2 photocatalysts, covering activated carbon, carbon doping, carbon nanotubes, [60]-fullerenes, graphene, thin layer carbon coating, nanometric carbon black and more recently developed morphologies. Mechanisms of enhancement, synthesis routes and future applications are summarised and discussed. New insight and enhanced photocatalytic activity may be provided by novel nanocarbon-TiO2 systems. Ongoing challenges and possible new directions are outlined.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Incorporation of nanocarbons with TiO2 enhances its photocatalytic activity. ► Enhancement is due to one or more of the three primary mechanisms discussed. ► Novel nanocarbon-TiO2 combinations have been developed in the past few years. ► These offer opportunities for the design of new photocatalytic systems.

Related Topics
Physical Sciences and Engineering Energy Energy (General)
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