Article ID Journal Published Year Pages File Type
1417175 Carbon 2007 7 Pages PDF
Abstract

A new polymeric amphiphilic molecule for dispersing carbon nanotubes (CNTs) in water, oligothiophene-terminated poly(ethylene glycol) (TN-PEG), was synthesized and its ability to stabilize aqueous CNT dispersions was examined by UV–Vis spectroscopy and transmission electron microscopy. It was observed that the TN-PEGs were strongly adsorbed onto the nanotube surface via a strong π–π interaction, and thus only gentle sonication causes exfoliation of CNT ropes and bundles into well-separated individual objects and small bundles comprising 2–10 tubes. The dispersion ability of the TN-PEGs and the long-term stability of their resulting dispersions were much better than commercial surfactants.

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