Structural characterisation of oxygen diffusion hardened alpha-tantalum PVD-coatings on titanium

•Cp-titanium was coated with tantalum.•Tantalum was deposited in alpha-modification with a (110)-preferred orientation.•By oxygen diffusion hardening, a hardness increase of 50% was observed.

Titanium substrates were coated with tantalum layers of 5 μm thickness using physical vapour deposition (PVD). The tantalum layers showed a (110)-preferred orientation. The coated samples were hardened by oxygen diffusion. Using X-ray diffraction the crystallographic structure of the tantalum coatings was characterised, comparing untreated and diffusion hardened specimen conditions. Oxygen depth profiles were determined by glow discharge spectrometry. The hardening effect of the heat treatment was examined by Vickers microhardness testing. The increase of surface hardness caused by oxygen diffusion was at least 50%.