Removal of Acid Orange 7 and Remazol Black 5 reactive dyes from aqueous solutions using a novel biosorbent

This study utilizes canola stalks (CS), an agro-residue, as a biosorbent to remove two different dyes, namely Acid Orange 7 (AO7) and Remozol Black 5 (RB5) from aqueous solutions. The effects of operational parameters on the efficiency of dye removal including pH, adsorbent mass, initial dye concentration and contact time have been investigated. For both tested dyes, the maximum absorption capacity was reached at initial pH 2.5 and 120 min contact time. The results showed that the absorption of both dyes depended on the pH of milieu, temperature, dye and CS concentrations. Freundlich and Langmuir models were used to analyze the obtained experimental data. The isotherms are found to be linear over the entire concentration range for both dyes. The highest value of linear correlation coefficients for AO7 (0.9926) and RB5 (0.9882) showed that the Langmuir is the best model to fit the experimental data. Kinetic study of absorption was done applying the pseudo first-order and the pseudo second-order equations. Absorption of both dyes could be well predicted by the pseudo second-order equation. The obtained results are very promising since: (i) high levels of dye removal (> 90%) were achieved with low contact times biosorbent/dye (less than 20 min contact); and (ii) the whole CS can be successfully used as biosorbent of AO7 and RB5 dyes in aqueous solution without needing any chemical modifications.

► Biosorption potential of low-cost canola stalk for the removal of direct dyes was investigated. ► Absorption of both dyes depended on the pH of milieu, temperature and CS concentrations. ► Langmuir model provided the best correlation coefficients of the experimental data. ► Absorption of both dyes could be well predicted by the pseudo second-order equation. ► High levels of dye removal (< 90%) at low contact times (< 20 min) biosorbent/dye were achieved.