| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1432620 | Polymer Science U.S.S.R. | 2006 | 8 Pages |
Abstract
It was found that polycondensation of methyltriphenylsilane, N,N′-bis-(trimethylsilyl) dimethyldiphenylcyclodisilazane and N,N′-bis-(trimethylsilyl)tetraphenylcyclodisilazane in the presence of catalytic amounts (1–2%) of metallic potassium takes place with the liberation of hydrocarbons and the formation of oligomers and polymers. It was found that it is accompanied by radical reactions of regrouping cyclodisilazane fragments. A mechanism was proposed for the initiation of various radical reactions taking place during polycondensation.
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