Microstructure and magnetic properties of nanostructured Fe–Co powders prepared by series of milling and annealing treatments

•Series 3 show a decrease in microstrain 2.5 times than series 1.•The HC decreases rigorously from 60 to 19 Oe for MA powders.•The MS increases for all series of powders.

Fe1−xCox(x = 0.1, 0.15, 0.2, 0.25, 0.3 and 0.5) powders were prepared by different milling-annealing treatments, and magnetic properties were investigated based on microstructure. Elevated heating times led to an increase in crystallite size, and decrease in lattice parameter. Up to 20 min annealing, series 3 powders showed a decrease in microstrain 2.5 times more than series 2. The coercivity (HC) of 1-step milled and 60 min annealed Fe50Co50 alloys decreased rigorously from 60 Oe to 19 Oe due to strain relief (from 0.3% to 0.08%) and grain growth (from 30 nm to 40 nm). For series 2 alloys, the HC (up to 60 min heating) increased from 72 Oe to 90 Oe, and decreased (up to 100 min heating) to 70 Oe. Compared to series 1, extra milling treatment of series 2 causes an increase in magnetization saturation (MS) due to completion of alloying and grain refinement. Also, compared to series 2, extra annealing treatment for series 3 resulted in larger values of MS caused by stain relief.

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