| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1440936 | Synthetic Metals | 2014 | 4 Pages |
•Synthesis of poly(2-methoxyaniline-5-phosphonic acid monoethyl ester) (PMAPE).•First example of the conducting self-doped polymers with phosphonic acid monoester.•High water-solubility of the pyridinium salt of the thus-obtained PMAPE.•Conductivity (1.3 S/m).•High transparency of the spin-coating film.
Poly(2-methoxyaniline-5-phosphonic acid monoethyl ester) (PMAPE) was synthesized via oxidative polymerization of 2-methoxyaniline-5-phosphonic acid monoethyl ester. This is the first example of the conducting self-doped polymers with phosphonic acid monoester. Self-doping of the polymer was shown by UV–vis–NIR and ESR measurements. The pyridinium salt of the thus-obtained PMAPE was water-soluble and its film exhibited conductivity.
Graphical abstractPoly(2-methoxyaniline-5-phosphonic acid monoethyl ester) (PMAPE) was synthesized via oxidative polymerization of 2-methoxyaniline-5-phosphonic acid monoethyl ester. Self-doping of the polymer was shown by UV–vis–NIR and ESR measurements. The pyridinium salt of the thus-obtained PMAPE was water-soluble and its film exhibited conductivity (1.3 S/m).Figure optionsDownload full-size imageDownload as PowerPoint slide
