Article ID Journal Published Year Pages File Type
1441501 Synthetic Metals 2012 5 Pages PDF
Abstract
► Dipolar self assembled monolayers consisting of benzoic acid molecules are grafted on top of ITO electrodes. ► Coated ITO samples of the type ITO/SAM/sexithiophene/Al are compared to bare ITO ones in order to reveal the influence of the SAM layer. ► Dramatic effect is observed on I-V characteristics under illumination depending on the dipole orientation of the SAM layer. ► A theoretical model is developed to relate the open circuit voltage to photogeneration rates at both electrodes. ► Experimental results are consistent with the model that predicts a shift of open circuit voltage depending both on molecular dipole magnitude and its orientation.
Related Topics
Physical Sciences and Engineering Materials Science Biomaterials
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