Tetrathiafulvalenium–bromide systems as nanosticks and nanoparticles stabilized by PEDOT

In this communication, we describe the first PEDOT-stabilized TTF-based nanoobjects (PEDOT: poly(3,4-ethylenedioxythiophene)). Two tetrathiafulvalenium–bromide systems, namely TTFBr0.59 and TTFBr, have been processed as nanosticks and well-dispersed nanoparticles in PEDOT, acting as a stabilizing agent. Nanopowders are studied by various techniques including infrared, Raman, X-ray diffraction, transmission electron microscopy, and transport measurements.