Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1442215 | Synthetic Metals | 2011 | 4 Pages |
The photoelectrochemical properties of poly(3-hexylthiophene) (P3HT) and poly(2,3-diethylquinoxaline-5,8-diyl) (PDEQx) thin films on ITO (indium-tin oxide) electrodes were investigated in aqueous media. Photoirradiation of the P3HT-coated electrode resulted in cathodic photocurrents in the presence of methyl benzoylformate, whereas the PDEQx-coated electrode generated stable anodic photocurrents in the presence of 2-mercaptoethanol. The action spectra indicate that photoexcitations of the polymers cause photoelectrochemical reactions. The films of P3HT and PDEQx exhibit a typical photochemical response of p- and n-type semiconducting materials, respectively.
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