| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1442509 | Synthetic Metals | 2008 | 5 Pages |
New carbazole-based polymers, which contain various content of electro-active fragments in the main chain connected via alkylene spacers, have been synthesized by Ni(0)-catalyzed Yamamoto-type aryl–aryl coupling reactions. These compounds represent amorphous materials of high thermal stability with glass-transition temperatures of 139–151 °C and thermal decomposition starting at temperatures above 400 °C. UV–vis absorption and photoluminescence emission spectra of the materials confirmed that the conjugated segments in the macromolecules are rather short. However, the polymers with varying content of the electro-active chromophores demonstrate different charge injection and transport properties in multilayer light emitting diodes with the polymers as the hole transport and tris(8-quinolinato)aluminium (Alq3) as the electroluminescent/electron transport layer. The device based on the polymer containing bicarbazole segments in the main chain exhibits the best overall performance (turn-on voltage: 4 V; maximum photometric efficiency: 2.6 cd/A; maximum brightness: approximately 2200 cd/m2).
