Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1443020 | Synthetic Metals | 2009 | 4 Pages |
Abstract
Optically active N-propargylamides polymerized with rhodium catalysts into helical polymers with predominantly one-handed screw sense. It was confirmed that hydrogen bonding between the amide groups in the side chains played an important role to stabilize the helical structure. Poly(1-methylpropargyl alcohol)s and the esters took helical structures stabilized by the steric effect of methyl group adjacent to the main chain.
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Related Topics
Physical Sciences and Engineering
Materials Science
Biomaterials
Authors
Fumio Sanda, Toshio Masuda,