Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1443027 | Synthetic Metals | 2009 | 4 Pages |
Abstract
Picosecond time-resolved infrared absorption spectra of the photoexcited states of a spin-coated film of regioregular poly(3-hexylthiophene) (RR-P3HT) have been recorded at 77Â K. The time-resolved photoinduced infrared absorptions due to electronic transitions at 2500Â cmâ1 and vibrational transitions at 1575Â cmâ1 have fast and slow decay components. By comparing the picosecond time-resolved infrared absorption spectrum of long-lived (slow decay component) transient species with the doping-induced infrared difference spectrum of RR-P3HT, the long-lived transient species are assigned to polarons. The short-lived transient species are assigned to singlet excitons and/or polaron pairs.
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Authors
Akira Sakamoto, Masato Takezawa,