Article ID Journal Published Year Pages File Type
1443039 Synthetic Metals 2009 5 Pages PDF
Abstract
Si (monosilane, disilane, and disiloxane) unit-bridged diphenylamine-containing poly(arylene) PARs were prepared and properties of PARs were compared with the relative Si unit-bridged diphenylamine homopolymers. PARs were prepared by palladium-catalyzed polycondensation between Si unit-bridged diphenylamine and distannyl- or diboryl-aromatic compound. PAR with disiloxane unit-bridged diphenylamine was also prepared by oxidation of PAR with disilane unit-bridged diphenylamine. Optical properties and electrochemical properties of PAR depended on not only bridging Si unit but also introduced arylene unit.
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Physical Sciences and Engineering Materials Science Biomaterials
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