Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1443039 | Synthetic Metals | 2009 | 5 Pages |
Abstract
Si (monosilane, disilane, and disiloxane) unit-bridged diphenylamine-containing poly(arylene) PARs were prepared and properties of PARs were compared with the relative Si unit-bridged diphenylamine homopolymers. PARs were prepared by palladium-catalyzed polycondensation between Si unit-bridged diphenylamine and distannyl- or diboryl-aromatic compound. PAR with disiloxane unit-bridged diphenylamine was also prepared by oxidation of PAR with disilane unit-bridged diphenylamine. Optical properties and electrochemical properties of PAR depended on not only bridging Si unit but also introduced arylene unit.
Keywords
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Authors
Hideki Hayashi, Hidenobu Nakao,