Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1443921 | Synthetic Metals | 2008 | 4 Pages |
Abstract
In this communication we describe the unprecedented ruthenium(II)-mediated synthesis of polyaniline. The synthesis enroutes via formation of a simple ruthenium(II)-tetraaniline complex which on chemical oxidation with hydrogen peroxide in the presence of hydrochloric acid gives conducting polyaniline-RuO2 composite. The reaction is novel in the way that both the metal center Ru(II) and the coordinated aniline molecules of the intermediate complex 1 take part in the oxidation reaction to yield polyaniline-ruthenium oxide hybrid.
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Authors
Chepuri R.K. Rao, M. Vijayan,