Role of trivalent Sr substituents and Sr vacancies in tetragonal and polar states of SrTiO3

Inelastic light scattering is used to study lattice dynamics of strontium titanate (STO) ceramics with several heterovalent dopants (La3+, Gd3+, Y3+), which substitute Sr2+ ions. An extraordinary shift of the antiferrodistortive transition temperature (Ta) is ascertained when just a small percentage of any of the dopants is used. Ta is dependent on the tolerance factor (t). In this work, it is clearly shown that, regardless of the dopant used, a common linear dependence of Ta vs. t is obtained if strontium vacancies are taken into account. A vacancy size of ∼1.547 Å was estimated, which is ∼7% larger than the Sr2+ radius. The vacancy size obtained can directly explain the increase in lattice parameter with increasing Bi3+ content in Bi-doped STO, as opposed to the dopants referred to above. Furthermore, the introduction of La3+, Gd3+ or Y3+ ions at the Sr site causes a considerable stiffening of the transverse optic TO1 mode at low temperatures, thereby decreasing the phonon contribution to the dielectric permittivity. Thus, no traces of a ferroelectric phase are found for any of the dopants used in this work.

Graphical abstractSr-substituents doping and compensation charge chemistry in SrTiO3 unraveled by giant tetragonality improvement. Sr-vacancy size is 1.547 Å.Figure optionsDownload full-size imageDownload high-quality image (142 K)Download as PowerPoint slide