Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1447316 | Acta Materialia | 2011 | 7 Pages |
The alloying effects of Mn, Co and Nb on the stacking fault energy (SFE) of austenitic stainless steels, Fe–Cr–Ni with various Ni contents, are investigated via quantum–mechanical first-principles calculations. In the composition range (cCr = 20%, 8 ⩽ cNi ⩽ 20%, 0 ⩽ cMn, cCo, cNb ⩽ 8%, balance Fe) studied here, it is found that Mn always decreases the SFE at 0 K but increases it at room temperature in high-Ni (cNi ≳ 16%) alloys. The SFE always decreases with increasing Co content. Niobium increases the SFE significantly in low-Ni alloys; however, this effect is strongly diminished in high-Ni alloys. The SFE-enhancing effect of Ni usually observed in Fe–Cr–Ni alloys is inverted to an SFE-decreasing effect by Nb for cNb ≳ 3%. The revealed nonlinear composition dependencies are explained in terms of the peculiar magnetic contributions to the total SFE.