Article ID Journal Published Year Pages File Type
1448466 Acta Materialia 2009 7 Pages PDF
Abstract

A simple kinetic model of the interaction between the Kirkendall effect and the inverse Kirkendall effect in hollow nano-shell formation by solid-state reaction is presented. The difference in vacancy concentrations at the inter-phase boundaries (and corresponding vacancy gradients) is taken into account as well as the curvature effect on the driving force of the reaction. A criterion for nano-shell formation is proposed.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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