Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1448466 | Acta Materialia | 2009 | 7 Pages |
Abstract
A simple kinetic model of the interaction between the Kirkendall effect and the inverse Kirkendall effect in hollow nano-shell formation by solid-state reaction is presented. The difference in vacancy concentrations at the inter-phase boundaries (and corresponding vacancy gradients) is taken into account as well as the curvature effect on the driving force of the reaction. A criterion for nano-shell formation is proposed.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
A.M. Gusak, K.N. Tu,