Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1448609 | Acta Materialia | 2009 | 9 Pages |
Abstract
The behavior of Mn when doped into ZnO by ion implantation was investigated by scanning transmission electron microscopy, electron energy loss spectroscopy and energy dispersive X-ray spectroscopy. Unlike the previously reported case of Co/Ni-implanted ZnO (where Co/Ni nanocrystals were observed), Mn implantation has been found to induce an O deficiency in ZnO, which results in the formation of hexagonal Zn nanocrystals when the implantation dose is sufficient. Further annealing of the high-dose Mn-implanted ZnO promotes the formation of ZnMn2O4 compounds near the surface and a porous structure within the implanted region. The fundamental reasons behind these physical phenomena are discussed.
Keywords
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Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Y. Wang, J. Zou, Y.J. Li, B. Zhang, W. Lu,