A new inorganic framework in the synthesis of barium carbonate nanoparticles via convenient solid state decomposition route

BaCO3, a common mineral with important applications in industry, has been synthesized in the orthorhombic phase with a high purity. As a new precursor, barium-o-phthalate complex was applied to prepare BaCO3 nanoparticles via solvent-free thermal decomposition route. Thermogravimetric analysis (TGA) was applied to determine the thermal behavior of the complex. The products were characterized by X-ray diffractometry (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FT-IR). The best results were obtained for the sample prepared at 500 °C. Transmission electron microscopy (TEM) of this product shows “bean-like” shaped nanoparticles with an average size of 35–70 nm. The purity, composition and stoichiometry of the as-prepared sample were studied by Electron Diffraction X-ray spectroscopy (EDX) spectra.

Graphical abstractBaCO3, a common mineral with important applications in industry, has been synthesized in the orthorhombic phase with a high purity. As a new precursor, barium-o-phthalate complex was applied to prepare BaCO3 nanoparticles via solvent-free thermal decomposition route. Transmission electron microscopy (TEM) of this product shows “bean-like” shaped nanoparticles with an average size of 35–70 nm.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Orthorhombic BaCO3 nanoparticles (35–70 nm) were prepared. ► The solid state decomposition route is introduced as an economical method. ► The results of SEM the smallest particle size and the best morphology.