Article ID Journal Published Year Pages File Type
1458684 Ceramics International 2016 6 Pages PDF
Abstract

Porous hydroxyapatite particles were synthesized by a self-assembly method. The process was carried out under a basic pH condition using cetyltrimethylammonium bromide (CTAB) as cationic surfactant and 1-dodecanethiol (RSH) as micelle size expander. The focus of the present work was to investigate the effect of synthesis temperature and pore expander content on the dissociation degree of 1-dodecanethiol and the degree of swelling in the micelle structure. Swelling was related to the electrostatic interaction between the dissociated 1-dodecanethiol molecule (RS−) and the cationic molecules of CTAB (CTA+). The synthesized samples were characterized by low-angle X-ray diffraction (LA-XRD), N2 adsorption–desorption experiments, X-ray diffraction (XRD) and field emission scanning electron microscope (FESEM). The results indicated that pore expander content as well as the synthesis temperature played a significant role in the swelling of the micelle structure. There was a decrease in particle length/diameter ratio with the increase in the synthesis temperature and pore expander concentration. Nanoparticles with pore size in range of 23–40 nm were obtained in this study.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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