Article ID Journal Published Year Pages File Type
1460213 Ceramics International 2015 8 Pages PDF
Abstract

The polycrystalline Nd-modified bismuth ferrite BiFeO3 (Bi1−xNdxFeO3 (BNFO) (x=0, 0.05, 0.15, and 0.25)) were prepared in a single-phase using a standard and cost effective solid-state reaction method. In order to check the quality and formation of the compounds x-rays diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive x-ray spectroscopy (EDAX) techniques were used. Preliminary structural analysis indicates that the crystal structure of BNFO is rhombohedra for its low content of Nd (x=0, 0.05, 0.15) whereas for higher content (x=0.25) it is tetragonal. The dielectric and ferroelectric properties of BiFeO3 (BFO) were dramatically enhanced on the above Nd-substitutions. Study of the frequency dependence of ac conductivity suggests that the materials obey Jonscher׳s universal power law. An increase in Nd-content in BNFO results in the enhancement of spontaneous magnetization of BFO because of the collapse of spin cycloid structure.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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