Article ID Journal Published Year Pages File Type
1467410 Composites Part A: Applied Science and Manufacturing 2009 6 Pages PDF
Abstract

The effect of moisture adsorbed on BaTiO3 on the properties of cyanate ester (CE)/BaTiO3 dielectric composites is examined using undried and dried BaTiO3 particles. The influence of moisture on the dielectric constant, thermal stability, dynamic mechanical properties, flexural behavior and micro morphology of the composites is investigated. Dielectric constant (ε) and dielectric loss (tan δ) of composites with the dried BaTiO3 are both higher than composites manufactured with undried filler at the same frequency. The dielectric properties of the dried system are stable over a broader temperature range than the undried composites. Adsorbed moisture causes the initial decomposition temperature and the maximum degradation temperature of the composite to decrease by 27 °C and 15 °C, respectively. By removing the moisture from BaTiO3, the CE/BaTiO3 composite exhibits a lower modulus (E′), higher strength, higher flexural elongation and a dramatically increased glass transition temperature (Tg).

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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