Article ID Journal Published Year Pages File Type
1468332 Corrosion Science 2016 10 Pages PDF
Abstract

•Heat resistant alloys were corroded in high temperature CO2 at 0.1–20 MPa.•Oxide layer thickness increased by less than factor of 2 with pressure increase.•Width of amorphous C layer at oxide/matrix interface increased about factor of 2.•For Alloy 800HT, the depth of region with Cr-rich carbides was not affected.•Tensile properties of alloys corroded in CO2 at 0.1–20 MPa were similar.

Chromia-forming heat-resistant alloys were corroded in atmospheric CO2 (0.1 MPa) and supercritical-CO2 (S-CO2, 10 and 20 MPa) at 550–650 °C for 1000 h. The weight gain and the extent of an amorphous C layer at the oxide/matrix interface increased with increasing CO2 pressure from 0.1 MPa to 20 MPa, but the increase was mostly less than a factor of 2. Despite the huge difference in the test pressure, the depth of the carburized region with Cr-rich carbides was rarely affected for Alloy 800HT, resulting in similar tensile properties after corrosion in CO2 and S-CO2.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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