Article ID Journal Published Year Pages File Type
1468612 Corrosion Science 2015 5 Pages PDF
Abstract

The low corrosion rate of 3Cr steel is caused by prepassivation, which is believed to be related to the formation of a Cr(OH)3 layer on the surface of the steel, thus modifying the anodic reaction. The open-circuit voltage (OCP) of 3Cr steel exhibited a tendency to increase over time from −0.67 to −0.48 V. Simultaneously, the solution pH near the substrate decreased, which affected the cathodic reaction with the possible participation of the direct reduction of H+. Modifying both anodic and cathodic reactions maintains the OCP in the desired potential range, causing spontaneous prepassivation to occur.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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